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chemical stability : ウィキペディア英語版
chemical stability
Chemical stability when used in the technical sense in chemistry, means thermodynamic stability of a chemical system.〔(Definition of Stable in IUPAC Gold Book )〕
Thermodynamic stability occurs when a system is in its lowest energy state, or chemical equilibrium with its environment. This may be a dynamic equilibrium, where individual atoms or molecules change form, but their overall number in a particular form is conserved. This type of chemical thermodynamic equilibrium will persist indefinitely unless the system is changed. Chemical systems might include changes in the phase of matter or a set of chemical reactions.
State A is said to be more thermodynamically stable than state B if the Gibbs energy of the change from A to B is positive.
==Chemical stability versus reactivity==

Thermodynamic stability applies to a particular system. The reactivity of a chemical substance is a description of how it might react across a variety of potential chemical systems and, for a given system, how fast such a reaction could proceed.
Chemical substances or states can persist indefinitely even though they are not in their lowest energy state if they experience metastability - a state which is stable only if not disturbed too much. A substance (or state) might also be termed "kinetically persistent" if it is changing relatively slowly (and thus is not at thermodynamic equilibrium, but is observed anyway). Metastable and kinetically persistent species or systems are not considered truly stable in chemistry. Therefore, the term ''chemically stable'' should not be used by chemists as a synonym of ''unreactive'' because it confuses thermodynamic and kinetic concepts. On the other hand, highly chemically unstable species tend to undergo exothermic unimolar decompositions at high rates. Thus, high chemical instability may sometimes parallel unimolar decompositions at high rates.〔(Definitions of Unstable in IUPAC Gold Book )〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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